Alkanes (Saturated hydrocarbons)

Chemical constitution: saturated hydrocarbons

General formula: Cn H2n+2

Characteristic suffix: -ane

 

Number of carbon atoms in Formula Name Alkyl group (is derived from alkane by losing one atom of hydrogen)
1 CH4 methane CH3 - , methyl
2 C2H6 ethane CH3 -CH2 - , ethyl
3 C3H8 propane CH3 -CH2 -CH2 - , propyl
4 C4H10 butane CH3 -CH2 -CH2 -CH2 - , butyl
5 C5H12 pentane CH3 - (CH2)3 - CH2 - , pentyl
6 C6H14 hexane CH3 - (CH2)4 - CH2 - , hexyl
7 C7H16 heptane CH3 - (CH2)5 - CH2 - , heptyl
8 C8H18 octane CH3 - (CH2)6 - CH2 - , octyl
9 C9H20 nonane CH3 - (CH2)7 - CH2 - , nonyl
10 C10H22 decane CH3 - (CH2)8 - CH2 - , decyl

 

The alkanes are able to form a homologous series - they are differing from each other by the addition of CH2 groups.

Physical properties:

C1 - C4 = gasses

C5 - C16 = liguids

C17 and higher = solids

- colourless

- has a less density as a density of water

Structure:

1. Alkanes with straight chain

2. Alkanes with branched chain - they are able to form more than 1 structural forms it´s called constitutional isomerism

alkanes

The molecules have different structures formulae but they have same formulae. That is why they have different physical properites (e.g. boiling point) but similar chemical properties.

Alkanes (Saturated hydrocarbons)

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